What is chocolate and why is it delicious?

Well you've probably never heard of chocolate, and you've almost certainly never eaten it. But if you had you might wonder, what the heck is this? How do they make it? And why does it taste so gosh darn good?
Melissa:

Don't forget. Right now, Gemini are running a special campaign at our If you go to kodashfi.com/ chem for your life and subscribe at any amount, Gemini will send you a special chemistry for your life sticker. That's kodashfi.com/chem for your life to learn more about why we're doing this and how to subscribe. And now on to today's show. Hey.

Melissa:

I'm Melissa.

Jam:

I'm Jam.

Melissa:

And I'm a chemist.

Jam:

And I'm not.

Melissa:

And welcome to chemistry for your life.

Jam:

The podcast helps you understand the chemistry of your everyday life.

Melissa:

Okay, Jim. Today, we are going to respond to a question from listener and friend of this show K. My sister and yours, just kidding, just mine, Renee c.

Jam:

Renee. Okay. Awesome. This better be a good one. It was, like, quite an intro.

Jam:

She's got a lot of titles. So

Melissa:

Yeah. She does have a lot of titles. She has a really cool job. Go back and listen to our episode if the sea is rising and if we should be scared

Jam:

Mhmm.

Melissa:

But her question was, why is chocolate delicious?

Jam:

Oh, okay.

Melissa:

Okay. So what we're gonna address here in this episode is, what is chocolate? Why is chocolate delicious?

Jam:

K.

Melissa:

Is white chocolate actually chocolate?

Jam:

K.

Melissa:

Why is chocolate dangerous for dogs.

Jam:

K. I know a little bit about chocolate. Not so as much the, like, chemistry in-depth, but I ended up attending a chocolate tasting pre COVID. Wasn't it nice when we could just all Hang on a room and taste stuff and not worry about anyone getting sick and all that. But, anyway

Melissa:

the good old days.

Jam:

The good old days. Here's a question I have. Do scientists agree that chocolate is delicious? That seems like something that scientists need to figure out first.

Melissa:

Well, we're not gonna talk about necessarily the subjectivity about the deliciousness, but we are gonna talk about some molecules in it that make us really like it your crave it, kind of.

Jam:

Okay. Got it.

Melissa:

So that's how we're gonna address that.

Jam:

Nice.

Melissa:

But, also, there's so much to the chemistry of chocolate that next week, we're going to do another episode where we talk about why sometimes chocolate gets that weird white film on the outside side

Jam:

of it Oh, okay. Yeah. When it's old or whatever?

Melissa:

Mhmm. And we're gonna talk about what makes American chocolate different than other chocolates.

Jam:

Got it. Different meaning worse. Just kidding.

Melissa:

I mean, no comment. We'll we'll go into the scientific of that next week.

Jam:

Nice. Okay. Cool. Dude, I'm pumped. This is a great question.

Jam:

I love this. I'm ready to learn about this, and I'm kind of creating some predictions in my mind, I think, a little bit.

Melissa:

Okay. Well, I think it's gonna be a fun kind of all this and more today. So we've got a lot coming at you. So let's start first with what chocolate is.

Jam:

Okay.

Melissa:

Okay. It is a pod. There's a cocoa pod with seeds in it.

Jam:

Mhmm. Kinda like an iPad.

Melissa:

Like an ipod, except if you could break it open, and the seeds to me look like giant garlic

Jam:

cloves. Okay. Yeah.

Melissa:

They're white and but maybe kind of slimy a little bit. Mhmm. Slimy garlic cloves. They're white and about that shape, but a little bit bigger.

Jam:

K. I don't know.

Melissa:

Can you think of something else that's similar to the coco coco seed? Do you know what a cocoa seed looks like?

Jam:

I do have seen it. And isn't it called cacao, by the way?

Melissa:

Oh, I think it is called cacao. I always mix those up.

Jam:

But Maybe

Melissa:

maybe not.

Jam:

I think I mean, during the word, cocoa came from that, but, yeah, it's kind of a you know, it looks a little bit like the white part. My hand reminds me of, like, orange Oranges. Like

Melissa:

Oh, yeah. The little sections of oranges when they have the white part still on them.

Jam:

Although, this is actually slimy like you said, But it looks a little like oranges having the white stuff on it on the inside.

Melissa:

I think that's a good visual. So they take those seeds and they ferment them, and then they roast them.

Jam:

Nice. Nice.

Melissa:

And then they ground them

Jam:

up Uh-huh.

Melissa:

To make what's known as chocolate liqueur or liquor. I'm not really sure the proper way of saying because I read it.

Jam:

Yeah.

Melissa:

And the thing about that chocolate liquor liqueur is that it has the chocolatey flavor, but it doesn't have the right amount of fat to eat as, like, eating chocolate.

Jam:

Okay. Interesting. Fat.

Melissa:

So fat. Mhmm. And that fat that's in there is what's known as cocoa butter.

Jam:

Right. It's

Melissa:

got triglycerides in it. Mhmm. And so they actually separate out chemically Mhmm. The chocolate solids from the cocoa butter, the triglycerides from the fat. And that makes solid chocolate

Jam:

Mhmm.

Melissa:

And cocoa butter.

Jam:

Right. Right.

Melissa:

So for the cocoa butter part of that, you can add it in to other chocolate liqueur to become eating chocolate with the right fat content. They increase the fat content so it's the right kind of eating chocolate, and then they'll add a few other things to it maybe.

Jam:

Mhmm.

Melissa:

And then with the cocoa solids, that becomes cocoa powder that they use in chocolate candy making shop types things, and they'll use it in drinking hot chocolate kind of cocoa.

Jam:

And is the butter maybe this is wrong, but I thought that cocoa butter came from that white stuff. Is that correct?

Melissa:

That is not my understanding. Woah. My understanding is that they grind up the fermented pods and that the fermented roasted seeds, and that is chocolate liquor

Jam:

And then

Melissa:

and then

Jam:

they separate the butter out. Yes. Okay. Different. Cool.

Jam:

Cool.

Melissa:

K. So that is the basics of cocoa and chocolate.

Jam:

Okay.

Melissa:

Now the cocoa butter is basically the foundation for white chocolate.

Jam:

I have heard that, and I've heard that white chocolate has 0 cacao solids. Is that true?

Melissa:

That is true. White chocolate is just cocoa butter, maybe some sugar, some dried milk, some vanilla for flavoring.

Jam:

Uh-huh.

Melissa:

So it's made from the cacao seeds that are roasted so I think it sort of does count as chocolate because it comes from those pods, the cacao pods

Jam:

Uh-huh.

Melissa:

But it doesn't have any of those chocolate solids in it.

Jam:

Yeah. Okay. Interesting.

Melissa:

And because of that, it is missing some of the important molecules that give chocolate not only its flavor, but also its health benefits.

Jam:

Okay.

Melissa:

So it is from the same plant

Jam:

Right.

Melissa:

But it is missing a key component.

Jam:

Right. Right. Right.

Melissa:

And actually 1 paper I read said that they're trying they have tried to make, quote, healthier, unquote, white chocolate that adds some of these beneficial molecules back in, which kinda makes me laugh. Because if you're trying to be healthy, white chocolate's probably not the way to go.

Jam:

Right. Yeah. Or it's like get your healthy stuff somewhere else. Like, have a salad and then have some white chocolate. Totally fine.

Jam:

You know?

Melissa:

Yeah. So that's the beginning answer to is white chocolate actually chocolate and what is chocolate?

Jam:

Right. Right. Okay. I'm with you.

Melissa:

But let's get into why chocolate is delicious to us, why some people most people perceive chocolate to be delicious.

Jam:

Yeah. It's got such a unique taste, but it's also I mean, Some in desserts have some version of chocolatey something in it. It's like Yes. It is kind of number 1 MVP of dessert.

Melissa:

There was a chocolate scientist who said he will give his students chocolate and tells them to describe it, and they say it tastes like chocolate. Like, usually, that's the response that he gets, which makes me laugh.

Jam:

That's good. I feel like I would do that and then feel like, oh, that was stupid. Like, I would say it. And then once I say The word is like chocolate. I'd say chocolate.

Jam:

I'd be like, gosh. Dang it. Like, that was

Melissa:

But how else do you describe it? You know?

Jam:

Yeah. I don't know, man. That's crazy.

Melissa:

So each chocolate square

Jam:

Mhmm.

Melissa:

Contains about 800 different molecules that give it the flavor and texture that we love. 800. Wow. I know. These include caffeine, which can be addictive.

Melissa:

Nice. But, actually, it's a lot less caffeine than many people think, but it does have a very similar structure. It's basically the same structure as caffeine with 1 of the hydrogens subbed out for a carbon group.

Jam:

Mhmm.

Melissa:

One carbon with some hydrogens around it. But because of that one change molecularly

Jam:

Mhmm.

Melissa:

It gives us smoother stimulation. So it's still a stimulant, makes us feel awake, buy into those same things, check out our episode on why caffeine makes you not sleepy.

Jam:

Mhmm.

Melissa:

So but it makes you less jitter jittery. So it's still a stimulant, but it's a more smooth stimulant.

Jam:

Got it. Okay. Cool.

Melissa:

It also has Phenylethylamine, which is that's a big scary word.

Jam:

Yeah.

Melissa:

It basically is similar to amphetamines, which we know are addictive and also millets.

Jam:

Yeah. When you say that word, I it had ended up having about, like, 2 more syllables than I expected. Like, you were still saying the word By the time I thought you would already have been done 2 syllables ago.

Melissa:

Oh, welcome to Organic Chemistry, man. It just those go on and on. And there's also a a cannabinoid present in chocolate, which is in the same family as the active ingredient in marijuana. Uh-huh. Plus there's sugar, which, of course, is delicious.

Melissa:

And may or may not have addictive properties, but we love it.

Jam:

Mhmm. Mhmm.

Melissa:

And there's all there's milk and possibly some vanilla flavoring, all the fats from the cocoa butter, so we have all kinds of things in there. Okay. Plus are you ready for this?

Jam:

Yes. There's more weird. Okay.

Melissa:

There are polyphenols. Okay. Again, the return of polyphenols.

Jam:

Okay. Interesting. They're back.

Melissa:

We talked about them in the tans episode and I think also in the maple syrup episode, so go check those out. And they those are the naturally occurring in plants. They're abundant in even in chocolate. Mhmm. And they are thought to, this is a new fact about it, contribute to the antioxidant properties that chocolate has.

Melissa:

And to learn more about antioxidants, we also did an episode about that. This is pretty fun. We're starting to get a pretty expansive library. I was

Jam:

gonna say, yeah. It's, like, happening more and more frequently where a topic brushes up against a little bit Of a topic or 2 or in this case, like, 3 that we Right. Already touched on, which is cool.

Melissa:

Yes. So all these things combine together to make chocolate delicious. And a lot of these things are what is missing from white chocolate, you know, there's no polyphenols to give us the antioxidant properties. There's none of these stimulants. There's none of the these things that will give it its subtle flavor.

Melissa:

These 800 different molecules, it's basically just triglycerides from what I could tell in the cocoa butter, and then you mix it with other stuff. So it doesn't have this complexity of flavor.

Jam:

Right. Right. Right. Got it.

Melissa:

Okay. So that's the very basics on what chocolate is.

Jam:

Okay.

Melissa:

There's a lot more chemistry to talk about with chocolate, we can talk about the chemistry of tempering chocolate, and then we're gonna touch more next week on some of those other things about chocolate

Jam:

Mhmm.

Melissa:

But I wanted you to take a stab at giving that back to me, and then I'd reward you with a fun fact about what makes I don't know if this is fun. It's kind of a sad fact about what makes chocolate dangerous for dogs.

Jam:

K. Got it. Okay. Sweet. So chocolate comes from the cacao pod.

Jam:

Mhmm. They take the, cacao things out of the pot. I I wanna say they're called

Melissa:

Seed?

Jam:

I I think some people call them nibs.

Melissa:

Oh, no. That's something different.

Jam:

Oh, is that after very processed?

Melissa:

It's after winnowing that nibs are, I think, obtained.

Jam:

Wow. This is

Melissa:

So I didn't go too in-depth onto that.

Jam:

So this is just the little seeds before anything's happening.

Melissa:

This is just the white, fleshy seeds.

Jam:

So they take the seeds. They ferment them. Mhmm. Then they roast them.

Melissa:

Mhmm.

Jam:

Then they crush them down.

Melissa:

Mhmm.

Jam:

And then they separate the Fats, the butter part from the cacao solids

Melissa:

right

Jam:

Using something called chemistry, which is a complete mystery to this podcast, but you know?

Melissa:

Oh, also, I was gonna say that that chocolate liquor is close to solid at room temperature, so I I think they do have to heat it up probably to do some of that extraction.

Jam:

Oh, gotcha. I

Melissa:

don't know why they call it the chocolate liquor because when I think of liquor, I think of, like, a liquid.

Jam:

Yeah. But I don't know. That's weird. I can almost say like, wanted to call it just concentrate or something like that, but or pure. Yeah.

Jam:

I don't know. Who knows?

Melissa:

I don't know.

Jam:

So it's in this liqueur form, and they and that's when they separate out the Cocoa butter from the cacao solids. Right?

Melissa:

That is the when it's in that semi solid needs to be heated up, that's when they separate out the bats from the solid. Right.

Jam:

Got it. Okay. Cool. So Then they put the solids into, you know, our various ways of eating chocolate with Some of the cocoa butter and depending on what you're eating, there might be some milk and also there's always sugar, maybe some other Flavors or whatever. But in that cacao solid already, there's a lot of already chemical stuff going on that's cool.

Jam:

Lots of different kinds of Mhmm. Molecules, and some caffeine that's slightly different And it gives us smoother stimulation from it instead of a Punchy, suddenly awake vibe that we get from coffee.

Melissa:

And that one's called theobromine.

Jam:

Theobromine. And there's also polyphenols Mhmm. And that has some of the cool antioxidant properties that are nice to have in chocolate. Mhmm. And, Oh, what else did you say?

Jam:

I'm kinda forgetting now.

Melissa:

That's the case. Yeah. A lot of weird. Of them. Right.

Melissa:

There is also, Phenylethylamine, which is similar to amphetamines and a cannabinoid. Oh, okay. Also, you know, 795 other different molecules present. So those are just ones that I thought I pulled out, I thought were interesting and contributed, but to the flavor and to the feeling that we get of why we like it so much.

Jam:

Right.

Melissa:

But there's so much more to that chocolate flavor than just those, there's 800 molecule in a chocolate square.

Jam:

Yeah. So it's very complicated, and we will name all of them 1 by 1 Starting now.

Melissa:

Absolutely not. That would not be the fun podcast.

Jam:

Oh gosh.

Melissa:

So you're you got most of them. I'm impressed.

Jam:

And then I guess this is the last thing that to kind of finish my summary is that then white chocolate has Is mostly just the cocoa butter

Melissa:

Mhmm.

Jam:

With some of the stuff in it, and is a lot less complex and does not have some of the coolest Chocolate elements to it.

Melissa:

Right.

Jam:

So bummer.

Melissa:

So, yeah, when people say, is white chocolate real chocolate? I mean, it depends on which you could argue both sides. It depends on what you're defining as chocolate.

Jam:

Right.

Melissa:

You know? Right. So Also, I looked up just a quick Google search

Jam:

Mhmm.

Melissa:

The the definition of a cacao nib.

Jam:

Mhmm.

Melissa:

And so it's those those beans or those seeds that are when they're crushed. So I guess that's what it means after winnowing. So it's like little pieces of that would maybe be it.

Jam:

Got it.

Melissa:

But when they're crushed, not so so small to be the liqueur is my understanding.

Jam:

Mhmm. Okay. Okay.

Melissa:

Yikes, some chocolatier from Switzerland is gonna send us an Instagram message about how wrong we are or something. I'd love to hear from some chocolatiers about how they make chocolate. When my mom and I were in Switzerland, we watched a chocolate show, and it was really beautiful and delicious.

Jam:

Wow. Yeah. I mean, it's cool that there's people who this is their area. This is their expertise. So that's kinda awesome.

Jam:

So Sorry.

Melissa:

Right.

Jam:

Guys. But also very cool, and let's talk.

Melissa:

Yeah. Definitely. Just we're just doing a quick overview, we'd love to be corrected or talk more about the detail.

Jam:

Yes.

Melissa:

Okay. So Now let's talk about why chocolate is lethal for dogs.

Jam:

Okay. Okay.

Melissa:

It's actually because of that theobromine, that caffeine like substance that's in chocolate.

Jam:

Okay. Interesting.

Melissa:

So this is toxic actually to humans too in the right amounts, but it has to be crazy amounts, kind of like how water can kill you if you have a ton or caffeine can kill you if you have a ton of it. You know? Mhmm.

Jam:

Or if you're submerged in the water for too long, it's also not good.

Melissa:

Yeah, definitely not good. So in dogs, they have a much lower tolerance, I think, because it affects their central nervous system like ours, but they have, I guess, such smaller systems that it just kind of overwhelms them. You know what I mean? Mhmm. Mhmm.

Melissa:

And so it stimulates their system, and then they have these negative side effects. So they have some vomiting or digestive issues, and then they can have twist twitching muscles and all this stuff. And then, eventually, they probably have a heart attack.

Jam:

Wow.

Melissa:

So and the the the theromine is it's metabolized slowly, so it can take about a day for the effects to appear. Mhmm.

Jam:

And

Melissa:

it can take several days for recovery. And there's not really an antidote, but usually they just induce vomiting.

Jam:

Mhmm. Mhmm.

Melissa:

So the lethal dose of theobromine for dogs, it's about a 100 to 500 milligrams per kilogram.

Jam:

Okay.

Melissa:

So in for our American listeners, that is about a 100 to 500 milligrams per 2 and a 2.2 pounds. Is that what we said? 2.2 pounds? Yeah. Yeah.

Melissa:

So Jam knew that conversion off the top of his head. So, you know, if you have a small dog, the bect could be significantly long larger than if you have a a 70 pound dog. It's gonna affect their systems differently. The larger the dog, the more they'll be able to handle it.

Jam:

Yeah. Yeah.

Melissa:

But just for reference, you know, not all chocolates have the same amount of theobromine. Cocoa powder contains a lot more than milk chocolate. You know? Uh-huh. Cocoa powder has about 10 times as much theobromine as milk chocolate does.

Jam:

Okay.

Melissa:

So just let's say your dog eats half a cup of cocoa powder.

Jam:

K.

Melissa:

Okay. For a 2 pound dog, the lethal dose would be probably around a100. Could they could tolerate up to 500, but a 100 is where it starts getting dicey Uh-huh. Milligrams for them.

Jam:

Okay.

Melissa:

To they had half a cup cup of cocoa powder, that would be a 1,000 milligrams.

Jam:

So So

Melissa:

that's 10 times.

Jam:

Yeah. Well above.

Melissa:

Well above.

Jam:

Yikes. Dang it, dude.

Melissa:

But if you had a dog that was £20

Jam:

Mhmm.

Melissa:

Then they would probably be able to handle half a cup just fine. If you're like my roommate and you have an 80 pound dog, half a cocoa cup of cocoa powder might not hit them even at all.

Jam:

And sometimes but science can't always explain is how my Thirty something pound beagle ate an entire chocolate bar one time and was fine. Although, I think he actually threw it up himself. Anyways Well,

Melissa:

also, if it was milk chocolate, it would only be 2 milligrams per gram. That was probably only, like, a 10 gram bar, so it's probably only 20 milligrams. So it's probably north close to the lethal nest.

Jam:

Nice. That explains it. Also, he did he nothing will kill him probably is the other thing I've I've come up with. That might be part of it too, but Also, it probably helped that he probably didn't have much the dibromine in there.

Melissa:

Yeah. He probably cleared up before it could fully be digest it also. Yeah. So definitely not giving chocolate to dogs. Yeah.

Melissa:

There is some some kind of theobromine free chocolate that you can give to dogs, but better to just avoid it. And if anything happens to your dog, maybe don't panic depending on their size, but get help quickly because it can be dangerous.

Jam:

Dang. That's crazy. Also, I would not have predicted that was the part of chocolate that caused the problem, like the caffeine part related to that section of All the many things that are in

Melissa:

I know.

Jam:

Chocolate. You said 800. It's like but that's just that one is also the one? That's just strange to me.

Melissa:

I wonder how caffeine affects our system. After reading this, I wondered if it had a similar effect, but we don't feed our dogs caffeine very much. Or maybe it's easier to process because that 1 methyl group is missing. You know? I don't know.

Jam:

My dog has also drank an entire cup of coffee and then then threw it up. So

Melissa:

wow. He

Jam:

he keeps protecting himself by just getting rid of it all. I don't know.

Melissa:

Yeah. He just does the hard work for you.

Jam:

Yeah. The.

Melissa:

So that is the chemistry of chocolate.

Jam:

Wow, dude. Crazy. I'm interested in this. I'm I wow. That's complicated.

Jam:

There's a lot more Better than I expected.

Melissa:

There is, and we didn't even scratch the surface of we'll scratch the surface next week, but this week, we didn't even scratch the surface of how chocolate is tempered and the crystal structure of chocolate is wild. So

Jam:

Well, awesome. I'm excited. These couple of Chocolate episodes sound like they're gonna be pretty sweet. Uh-huh. Did anything sweet happen in your week this week, Melissa?

Melissa:

Well, yes, Jam. You already know the answer to this question.

Jam:

Leading the Witness.

Melissa:

But Very exciting thing happened this week, actually, is me and my significant other got engaged.

Jam:

Nice. Congrats.

Melissa:

And, actually, Jam was there. It was under the ruse of a fun trip with the 4 of us up to Oklahoma to a place called Turner Falls that I love. I love waterfalls, so I was really excited. We've been trying to go since last March when COVID happened, and we're finally safely able to go.

Jam:

Yes.

Melissa:

And it was very fun and sweet and special. So yay.

Jam:

Dude, awesome. Congrats. Yes. It was very sweet. It was cool to get to witness that.

Jam:

I'm very excited for you guys.

Melissa:

I'm very excited too. And, actually, because of COVID and just the way things are right now, we're thinking of getting married pretty quick and having it mostly on Zoom, so you'll probably get that news again sometime soon. So, yay, this is very exciting. And

Jam:

thanks for

Melissa:

taking such cute pictures, jam. It was really nice to get to share that with someone, and it is beautiful. This is a perfect background for that.

Jam:

Oh, dude. Yeah. It was a nice day, great weather, cool waterfalls. Yeah. That was awesome.

Melissa:

And we had fun exploring the park together also even before that happened. So that probably would have been my happy thing from the week either way.

Jam:

Totally. And I'm not gonna share one because I cannot I cannot beat you getting engaged, but I'll just say that it was also cool for me to get to hang out with you guys. And if even if y'all didn't get engaged, I probably would've said the same thing. I'd be like, oh, we gotta go to this awesome waterfall and walk around this park. So definitely definitely, Was cool all around.

Melissa:

It's very, yeah, really fun. Definitely the highlight of our week. So, yay, I'm getting married to mason, he's great. You guys have heard me talk about him some on the show already when we wrapped up the last year. He's been such an awesome support system to me in my school and through my mom being sick, and he also loves the podcast and helps us out with this whenever he can too.

Melissa:

So Yeah. Yay. Thanks so much, Mason, for being awesome and a great person, and I'm so excited to marry you.

Jam:

Kim, she figured I approved.

Melissa:

Yay. So that is that's my great news, and I was so excited to share with all of you listeners because it feels like y'all are our friends just that we haven't met yet. So I I was thinking it would be really fun to share this with y'all. To thanks for always being excited and caring about our life events, you guys. We've heard a lot of good things on that part of our show each week, and Thanks for coming and listening and learning about chocolate.

Melissa:

I'm so excited to share more about this topic next week, and I'm so thankful for you guys. We both are because we literally could not do this show without you. So thank you so much.

Jam:

Absolutely. And thank you for teaching us, Melissa. And if you guys have ideas or questions, things you wonder about in your everyday life That may or may not be chemistry, please ask us. We'd love to hear your ideas. You can reach out to us on Gmail, Twitter, Instagram, or Facebook at chem for your life.

Jam:

That's chem, f o r your life to share your thoughts and ideas. If you'd like to help us keep our show going and contribute to cover the cost of making it, Go to kodashfi.com/chem for your life, and donate the cost of a cup of coffee. And don't forget, From now to the end of May, you go to our and sign up for a monthly subscription of any amount. We will send you a an exclusive sticker That's super cool, designed by a friend of ours, and also a note to say thank you from Melissa and I. But if you're not able to donate, you can still help us by subscribing in our favorite podcast app and rating and writing our review on Apple Podcasts.

Jam:

That also helps us to share chemistry with even more people.

Melissa:

This episode of Chemistry For Your Life was created by Melissa Collini and Jam Robinson. References for this episode can be found in our show notes or on our website. Jim Robinson is our producer, and we'd like to give a special thanks to s Navarro and v Garza who reviewed this episode.

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